Zoback and Gorelick
have just published a paper that a) emphasizes the vast amounts of carbon
dioxide that need to be captured and stored, and b) analyzes in detail the
likelihood that small-scale earthquakes may be induced at the injection sites
because of the increased fluids introduced into the storage sites. Their concern is that even small to medium
scale earthquakes may destroy the integrity of the sites, leading to
significant leakage of carbon dioxide back into the atmosphere. They conclude that extensive deployment of
carbon storage involves considerable risk.
Background. Zoback
and Gorelick have analyzed the long-term geological storage of carbon dioxide
(CO2) as a means of permanently removing this greenhouse gas from
the atmosphere by carbon capture and storage (CCS ; see the next section). First we present some introductory
information on CCS . (Background on CCS may be found in this earlier post.)
The European
Union (EU) has embarked on
the only multinational program in the world, based on binding enacted policies,
to reduce emissions below the emissions levels of 1990 by 20% by 2020, and by
80-95% by 2050 (the EU Roadmap; see this post). Achieving such goals requires decarbonization
of most energy sources. The EU
recognizes that a major portion of this reduction should come from use of CCS for large scale fixed sources involved in
generating electricity.
To begin research
and development of CCS technology, the EU has selected six
demonstration projects in six member countries, using differing capture and
sequestration technologies. The EU has
committed EUR1 billion (US$1.25 billion) to them. Variously, they range in size from one at 30 MW
(to be scaled up to over 300 MW) to 900 MW, with most projects expected to
capture about 90% of the emitted CO2. Storage will be in land-based or offshore
saline aquifers, and depleted land-based or offshore gas fields.
In the U. S. the state of California is implementing a plan very similar to the
EU’s Roadmap. In a non-official report
detailing how California might attain these goals, the California Science and
Technology Council (CSTC) relies heavily on decarbonizing energy sources to the
greatest extent possible (see this earlier post). Electricity generation is to be decarbonized,
to the extent that use of fossil fuels is maintained, by use of industrial-scale
CCS , even though the report recognizes that
this technology remains unproven.
Decarbonization of electricity generation is especially important
because CSTC envisions use of electric vehicles to decarbonize transportation.
The U. S. Department of Energy (DOE) is sponsoring research on CCS , as reported in the Carbon SequestrationProgram: Technology Program Plan
of the National Energy Technology Laboratory.
Its budget request for Fiscal Year 2011 was about US$140 million, with
anticipated sharing by an equal amount from Regional Carbon Sequestration
Partnerships with universities and corporations. This budget has grown from about US$10
million in 2000. Recent support from the
American Recovery and Reinvestment Act of 2009 (the fiscal “stimulus”),
included in the recent growth of this funding, is essentially exhausted at this
time. All aspects of the various stages in capture, release and concentration,
transportation and geological storage, as well as monitoring, verification and
accounting, are being investigated at laboratory and small pilot scale.
Similar programs
are also supported in the DOE Fossil Energy program. Their requested budget for Fiscal Year 2013
is about US$276 million for CCS
and Power Systems, which supports projects as large as industrial scale pilot
projects.
Cautionary
Analysis of CCS . Zoback
and Gorelick analyzed the dangers to maintenance of reservoir integrity in
geological sequestration of CO2, in a paper published in the
Proceedings of the National Academy of Sciences, June 26, 2012, vol. 109, pp.
10164-10168
. As background, the authors note:
·
CCS will be very costly;
·
in the U. S. use of coal for generating electricity
produces about 2.1 billion metric tons of CO2 a year, or about 36%
of all U.
S.
emissions;
·
China ’s emissions are about 3 times more than
this from coal-fired generation, corresponding to about 80% of its emission
rate;
·
annually,
on a worldwide basis, CCS has to contend with 3.5 billion tons of CO2,
which requires injecting an amount of CO2 underground roughly equal
to the volume of all the oil extracted from oil wells worldwide;
·
this
amount of injected CO2 requires that worldwide about 3,500
functional industrial-scale injection facilities be operational by mid-century,
averaged to about 85 facilities added per year; and
·
geological
storage must remain faultlessly leak-tight in order to compare with freedom
from emissions of renewable energy sources.
The authors include
the following analyses:
o
The
paper itemizes several instances of earthquakes apparently triggered by underground
injection of liquids. This can arise
because many geological formations are already in states of unresolved stress,
so that the relatively minor perturbation arising from fluid injection releases
the stress in an earthquake. The fluid in
essence makes it easier for the stressed surfaces to slide over one another,
which is the hallmark of an earthquake.
Zoback and Gorelick emphasize that it is not any land-based earthquake
damage to human wellbeing that concerns them, but rather that even small
earthquakes, likely not to produce damage to structures, are likely to damage
the geological structures holding the pressurized CO2. CO2 could then readily permeate to
or near the surface, permitting release into the atmosphere and defeating the
intent of the storage in the first place. They present the results of calculations that
even a small earthquake of Magnitude 4 could induce slippage of several cm.
along a fault of about 1-4 km (0.6-2.4 mi).
o
In
stressed geological formations, it is not only the pressure of injected CO2
that is potentially hazardous, but also the rate of injection. More rapid pressure buildup is more likely to
trigger an earthquake event; the need to dispose of large volumes of CO2
would be an incentive for high injection rates.
o
A
widely known injection site is the Utsira formation of the Sleipner gas field
in the North Sea .
About 1 million tons of CO2 has been separated from natural
gas and reinjected below ground every year, for the past 15 years. There has been no earthquake activity to
date. The authors calculate that about
3,500 such sites would have to be identified and put into service to
accommodate storage needs projected for 2050 (most of which would be needed
right now, in fact). The authors
conclude “Clearly this is an extraordinarily difficult, if not impossible task”
if only geologically suitable sites are to be used.
o
Depleted
oil and gas wells, while seemingly attractive as potential injection sites, are
not numerous enough to satisfy the need, and are not necessarily located
conveniently for the need.
The authors
conclude “multiple lines of evidence indicate that preexisting faults found in
brittle rocks almost everywhere in the earth’s crust are subject to failure,
often in response to very small increases in pore pressure. In light of the
risk posed to a CO2 repository by even small- to moderate-sized
earthquakes, formations suitable for large-scale injection of CO2
must be carefully chosen.” Because of
the extremely large volumes of CO2 needing to be disposed of, the industrial-scale
CCS needed will be “extremely expensive and
risky for achieving significant reductions in greenhouse gas emissions”.
Certain CCS projects have been abandoned due to risk
and lack of financing. The very factors identified by Zoback and
Gorelick are echoed in these two recent news reports.
The Guardian
on June 17, 2012 reported that Ian Marchant, chief executive of Scottish and
Southern Energy, while still favoring CCS development, warned the British Parliament
that a CCS project his company is undertaking is “the
most risky project I’ll ever invest in….CCS is…at the demonstration stage….We do not
know that this technology will work”. He
called for UK government support at this demonstration
phase of the project.
The same article
noted that another company, Scottish Power, abandoned CCS technology last year. Together with Shell, the company evaluated it
would need at least £1.5 billion (US$2.3 billion), and the UK government could not support such a funding
level.
Similarly, theGuardian reported
on June 26, 2012
that Ayrshire Power (Scotland ) abandoned its planned new CCS -fitted 1852 MW power plant because it
feared it could not obtain funding from the UK and the European Commission. Nevertheless, the Scottish energy minister
still strongly supports CCS development since it borders North Sea offshore CO2 storage sites.
Rebuttals of
Zoback and Gorelick’s warnings. There has been response from the CCS community rebutting the serious concerns
expressed by Zoback and Gorelick. For
example, two scientists were featured in the internet-based Carbon CaptureJournal (accessed June 27, 2012 ).
Dr. Malcolm Wilson,
Chief Executive Officer, The Petroleum Technology Research Centre (PTRC),
provided a detailed accounting of the experience gained at the Weyburn-Midale
Project, an oil field storage development project in Saskatchewan , Canada , which it seems is an extended oil recovery
project as well. Storage has been under
way there for 11 years, with a total of 21 million tonnes (metric tons) of CO2
stored in that time. Detailed research
and characterization of the site has been undertaken throughout this time;
indeed, seismic events with Magnitudes of -1 (extremely small) have been
recorded. Dr. Wilson considers this site
now to be industrial scale, as 2.8 million tonnes of new CO2, and
more than 5 million tonnes when recycled CO2 are included, have been
injected; no earthquake activity or leakage has been identified.
PTRC is also
conducting research on their Aquistore Project, for storage in saline
aquifers. Noting with approval that
Zoback and Gorelick cite aquifers favorably because of their very large storage
capacities, Dr. Wilson notes that the Aquistore Project will be the first
industrial scale storage project, since it will receive CO2 from a
coal-fired power plant.
Dr. Bruce Hill,
senior staff geologist at Clean Air Task Force (CATF) rebuts the concern over
lack of integrity of storage sites due to earthquake activity by emphasizing
the rate of CO2 migration toward the surface, rather than the total
amounts potentially released. Dr. Hill
emphasizes that there are many layers of rock structures, extending thousands
of feet, overlaying injection sites, seeming to belittle the concerns of Zoback
and Gorelick. Dr. Hill feels that the
examples cited by the authors are not representative. He points out that “approximately 1 billion
tons of CO2 have been safely injected (and stored) in the process of
enhanced oil recovery in the U.S. since the late 1970s, with no reported
seismic incidents. In fact, there have been no earthquakes reported anywhere
from saline CO2 injections either”.
Dr. Hill concludes
that CCS technology is “viable” and should play a
significant role in potentially storing the very large amounts of CO2
that need to be recovered to reduce atmospheric CO2 accumulation.
George Peridas
responded to the paper on the Natural Resources Defense Council Blog
on June 22, 2012 . Mr. Peridas believes that Zoback and Gorelick
raise valid issues, including whether CCS can cause earthquakes and whether such
earthquakes could lead to leakage of the injected CO2. But in his opinion, the conclusions reached
by the authors are more extensive than warranted by the evidence, for example
with respect to the second issue, leakage. He does not agree that an earthquake event
would lead to migration of CO2 all the way to the surface. He believes that an experiment cited by the
authors, performed on granite, a brittle mineral, is not representative of
capstone layers anticipated in CCS ,
which would be more compliant, yet impermeable, shales. In the case of existing fossil fuel
geological reservoirs, large earthquakes have been known to occur without loss
of the materials. Mr. Peridas
additionally cites Sally Benson (Stanford University and Lead Coordinating Author of the
Underground Geological Storage Chapter in the Intergovernmental Panel on
Climate Change Special Report on CCS ) as stating that naturally care must be
taken in choosing CCS injection sites, but that finding such sites
should be feasible.
Discussion
Our earlier post,
“Carbon Capture and Storage: A Needed yet Unproven Technology”,
presented background information on the various technologies that may be
employed in each phase of capturing CO2, from the burning of fossil
fuels for energy, to transporting the CO2 to a storage site, and finally
the actual storage process. Many
problems remain to make CCS industrially viable for utility-scale
facilities. Resolving these problems
requires investment of large sums of money, worldwide, to arrive at practical CCS by about 2020. Currently a relatively small number of
demonstration and pilot projects are under way around the world.
The use of fossil
fuels is projected to grow considerably in the coming decades around the globe,
primarily in developing countries which will power their rapidly expanding
economies with energy derived from burning fossil fuels. This means that the annual rate of CO2
emissions will continue expanding, and that the total accumulated
concentration of atmospheric CO2 likewise will continue
increasing. Even in developed countries
having programs to abate CO2 emissions at various stages of
maturity, a major aspect of such abatement involves shifting transportation to
electric power. Thus the total demand
for electricity is projected to grow in developed countries as well; to the
extent that this demand is not met by renewable sources the need for contending
with abatement of CO2 emissions likewise will grow. For this reason emission abatement programs
will rely ever more heavily on technologies such as CCS .
The paper by Zoback and Gorelick serves at
least three useful functions. First, by
arithmetic analysis, it underscores the vast, unprecedented need for functional
and effective injection sites projected by 2050. Some of this information has been summarized
above.
Second, its
geophysical modeling emphasizes the many unknown factors remaining in choosing
and developing new CO2 injection sites. The seals installed surrounding well bores,
and the many geological factors involved in retaining the injected CO2
out of contact with the atmosphere for hundreds or thousands of years must be
essentially fail-safe. Yet this work
emphasizes that the very act of injecting pressurized fluid facilitates
potential small-scale earthquakes that, according to the modeling, have the potential
of opening fissures in these seals that could lead CO2 back to the
surface.
Third, it has
engendered fruitful debate in the CCS community about the integrity of proposed
injection sites. Although these issues
were already known among workers in the community, they have now been aired
among a wider public. This has the
effect of ensuring that research and data gathering, involved in characterizing
new injection sites, will be carried out diligently and effectively so that
wise siting choices may be made.
The critics of Zoback and Gorelick, such as
those cited above, include examples in their rebuttals of injection sites
taking advantage of pre-existing wells used in the extraction of oil and gas
from their geological repositories.
These have kept the fuels underground for millions of years, and so are
cited as justifying CO2 injection for the same reasons. These are likely not representative of the
thousands of new storage injection projects that will be needed to accommodate
the demand. Overall the number of pilot
injection sites worldwide is small, and many are new experimental
projects. The concerns raised by Zoback
and Gorelick merit careful attention going forward as CCS technology is developed further and
deployed in number.
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